Direct catalytic asymmetric addition of acetonitrile to N-thiophosphinoylimines.
نویسندگان
چکیده
Direct catalytic addition of acetonitrile pronucleophiles to thiophosphinoylimines is described. Soft Lewis acid-hard Brønsted base cooperative catalysis is crucial to promote this elusive carbon-carbon bond-forming reaction in an enantioselective fashion.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 95 شماره
صفحات -
تاریخ انتشار 2013