Bis[benzyl N′-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-κ2 N′,S]nickel(II) N,N-dimethylformamide disolvate
نویسندگان
چکیده
In the title compound, [Ni(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the Ni atom (site symmetry ) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)°. In the crystal structure, an N-H⋯O hydrogen bond links the complex to the dimethyl-formamide solvent mol-ecule.
منابع مشابه
Bis{benzyl N′-[(1H-indol-3-yl)methylene]dithiocarbazato-κ2 N′,S}copper(II) N,N-dimethylformamide disolvate
In the structure of [Cu(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the Cu atom (site symmetry ) is N,S-chelated by the two deprotonated Schiff-base anions that define a distorted square-planar geometry. An N-H⋯O hydrogen bond links the mononuclear complex to the DMF solvent mol-ecules.
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