Bis{1-[4-(benzyloxy)phenyl]-4,4,4-trifluorobutane-1,3-dionato(1−)}dipyridinecobalt(II)
نویسندگان
چکیده
In the title compound, [Co(C(17)H(12)F(3)O(3))(2)(C(5)H(5)N)(2)], the Co(II) ion is situated on a twofold rotation axis, coordinated by four O atoms from two 1-[4-(benz-yloxy)phen-yl]-4,4,4-trifluoro-butane-1,3-dionate(1-) (L) ligands and two N atoms from two pyridine ligands in a distorted octa-hedral geometry. The two pyridine rings form a dihedral angle of 84.63 (7)°. The two benzene rings in L are twisted at 58.83 (5)°. Weak inter-molecular C-H⋯F hydrogen bonds consolidate the crystal packing.
منابع مشابه
Bis(pyridine-κN)bis[4,4,4-trifluoro-1-(4-fluorophenyl)butane-1,3-dionato-κ2 O,O′]cobalt(II)
In the structure of the title compound, [Co(C(10)H(5)F(4)O(2))(2)(C(5)H(5)N)(2)], cobalt(II) forms a complex with two 4,4,4-trifluoro-1-(4-fluoro-phen-yl)butane-1,3-dionate anions and two pyridine mol-ecules in an octa-hedral coordination environment, where the two dionate ligands are in equatorial positions and the two pyridine mol-ecules in axial positions. The complex is located on a crystal...
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