4-Nitrobenzoic acid–sulfathiazole (1/1)
نویسندگان
چکیده
In the crystal structure of the title compound, C7H5NO4·C9H9N3O2S2, the sulfa-thia-zole and 4-nitro-benzoic acid mol-ecules are held together by short π-π contacts between the thia-zole and nitro-benzene rings, with a centroid-centroid distance of 3.8226 (7) Å. The sulfa-thia-zole mol-ecules form dimers via N-H⋯N hydrogen bonds involving the thia-zole and sulfonamide moieties, owing to the fact that sulfathizole exhibits amide-imide tautomerism. The N-H (amine) groups of two sulfathiazole molecules are linked to the two S=O groups of a sulfathiazole via N-H⋯O hydrogen bonds. Two mol-ecules of coformer are held together by O-H⋯O hydrogen bonds. These units self-assemble, forming a three-dimensional network stabilized by (acid)C-H⋯π(sulfa-thia-zole benzene ring) inter-actions.
منابع مشابه
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In the title 1:1 adduct, C(7)H(5)NO(4)·C(7)H(7)NO(2), the nitro group of the 4-nitro benzoic acid is twisted from the attached ring by 4.40 (8)°. In the crystal, the mol-ecules are linked into ribbon-like structures along [150] and [10] via O-H⋯O, N-H⋯O, N-H⋯N and C-H⋯O inter-molecular hydrogen bonds.
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