Insertion and substitution chemistry at the boron fourth position in charge-neutral zwitterionic tripodal tris(methimazolyl)borate ligands.
نویسندگان
چکیده
A number of new charge-neutral zwitterionic tris(methimazolyl)borate ligands have been synthesized, either by substitution of the dimethylamine group in the adduct (dimethylamine)tris(methimazolyl)borane (1) or by insertion into its B-N(dimethylamine) bond by an unsaturated Lewis base. Two new anionic ligands, (thiocyanato)tris(methimazolyl)borate and (cyano)tris(methimazolyl)borate, have also been accessed by this method.
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ورودعنوان ژورنال:
- Inorganic chemistry
دوره 51 6 شماره
صفحات -
تاریخ انتشار 2012