An investigation of the hydrogen-bonding structure in bilirubin by 1H double-quantum magic-angle spinning solid-state NMR spectroscopy.

Supporting Information: Proton-Selective 17O–1H Distance Measurements in Fast Magic-Angle-Spinning Solid-State NMR Spectroscopy for the Determination of Hydrogen Bond Lengths

Solid-state NMR spectroscopy of molecular hydrogen trapped inside an open-cage fullerene.

Solid-state 1H experiments were performed an open-cage fullerene hosting molecular hydrogen. The anisotropy of the molecular hydrogen rotation was studied by double-quantum magic-angle-spinning NMR. The time scale of the molecular hydrogen rotation was estimated by spin-lattice relaxation measurements as a function of temperature.

Sensitivity enhancement and heteronuclear distance measurements in biological 17O solid-state NMR.

In this contribution we present a comprehensive approach to study hydrogen bonding in biological and biomimetic systems through 17O and 17O-1H solid-state NMR combined with density functional theory calculations of 17O and 1H NMR parameters. We explore the signal enhancement of 17O in L-tyrosine.HCl using repetitive double-frequency swept radio frequency pulses in solid-state NMR. The technique...

Identifying the intermolecular hydrogen-bonding supramolecular synthons in an indomethacin-nicotinamide cocrystal by solid-state NMR.

Two-dimensional (1)H double-quantum and (14)N-(1)H & (1)H-(13)C heteronuclear magic-angle spinning (MAS) NMR spectra recorded at natural isotopic abundance identify specific intermolecular COOH···N(arom) and CH(arom)···O=C hydrogen-bonding interactions in the solid-state structure of an indomethacin-nicotinamide cocrystal, thus additionally proving cocrystal formation.

Insight into Hydrogen Bonding of Uranyl Hydroxide Layers and Capsules by Use of H Magic-Angle Spinning NMR Spectroscopy

Solid-state H magic-angle spinning (MAS) NMR was used to investigate local proton environments in anhydrous [UO2(OH)2] (α-UOH) and hydrated uranyl hydroxide [(UO2)4O(OH)6·5H2O (metaschoepite). For the metaschoepite material, proton resonances of the μ2-OH hydroxyl and interlayer waters were resolved, with twodimensional (2D) double-quantum (DQ) H−H NMR correlation experiments revealing strong d...