Highly efficient hydrogenation of carbon dioxide to formate catalyzed by iridium(iii) complexes of imine-diphosphine ligands.
نویسندگان
چکیده
A new iridium catalyst containing an imine-diphosphine ligand has been developed, which showed high efficiency for the hydrogenation of CO2 to formate (yield up to 99%, TON up to 450 000). A possible catalytic mechanism is proposed, in which the imine group of the catalyst plays a key role in the cleavage of H2 and the activation of CO2.
منابع مشابه
Highly efficient hydrogenation of carbon dioxide to formate catalyzed by iridium(iii) complexes of imine–diphosphine ligands† †Electronic supplementary information (ESI) available: Experimental procedures; spectral data for all new compounds. See DOI: 10.1039/c5sc00248f Click here for additional data file. Click here for additional data file.
Carbon dioxide (CO2), an economical, safe, environmentally friendly, and renewable carbon source, is an ideal one-carbon building block for organic chemicals, including carbohydrates and fuels. However, its thermodynamic and kinetic stability presents a fundamental obstacle to the use of CO2 in both academia and industry. High-energy reagents, harsh reaction conditions, and special activation m...
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ورودعنوان ژورنال:
- Chemical science
دوره 6 5 شماره
صفحات -
تاریخ انتشار 2015