Chiral MOP-phosphonite ligands: synthesis, characterisation and interconversion of η1,η6-(σ-P, π-arene) chelated rhodium(I) complexes.
نویسندگان
چکیده
The synthesis of rhodium(I) and iridium(I) complexes of chiral MOP-phosphonite ligands is reported. The full characterisation of η(1),η(6)-(σ-P, π-arene) chelated 18VE rhodium(I) complexes reveals hemilabile binding on the arene which has been quantitatively analysed.
منابع مشابه
Chiral MOP-phosphonite ligands: synthesis, characterisation and interconversion of η,η-(σ-P, π-arene) chelated rhodium(I) complexes†
Monodentate phosphorus ligands based on the MOP architecture are proven as valuable ligands in asymmetric catalysis. It is widely recognised that these ligands can act as P,arene bidentate chelates to stabilise coordinatively unsaturated electron deficient metal centres. As such, hemilabile arene interactions are anticipated to be present, or indeed imperative, in catalytic processes. Whilst pa...
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 18 شماره
صفحات -
تاریخ انتشار 2013