Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclohexane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ2 N 1,N 11)rhenium(I)
نویسندگان
چکیده
In the title compound, [ReCl(C16H18N4)(CO)3], the Re(I) ion is coordinated in a distorted octa-hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo-hexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N-H⋯Cl hydrogen bonds link complex mol-ecules, forming a two-dimensional network parallel to (100).
منابع مشابه
Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ2 N 1,N 11)rhenium(I)
In the title compound, [ReCl(C15H16N4)(CO)3], the Re(I) ion is coordinated in a distorted octa-hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo-pentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N-H⋯Cl hydrogen bonds link comp...
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The title compound, C(16)H(10)N(2)O(5)S, was synthesized via the condesation of dihydro-thio-phen-3(2H)-one 1,1-dioxide, 1H-indene-1,2,3-trione and malononitrile in ethanol. The 2,3-dihydro-thio-phene 1,1-dioxide and pyran rings adopt envelope conformations. The mean planes through the planar part of the pyran ring and the benzene ring are nearly perpendicular, forming a dihedral angle of 88.40...
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In the title compound, [Mn(3)(C(8)H(10)O(4))(3)(C(18)H(10)N(4))(2)], one Mn atom and one cyclohexane-1,4-dicarboxylate (chdc) ligand are located on centres of inversion. One of the two independent Mn atoms is seven-coordinate, binding to five carboxyl-ate O atoms from different chdc ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2',3'-c]phenazine (L) ligand, while the second Mn atom...
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In the title compound, C14H19BrN2O2S, the 1,2,4-thia-diazinane ring adopts an envelope conformation with the N atom (attached to the sulfonyl group) as the flap, while the cyclo-hexane ring adopts a chair conformation. The mean plane of the cyclo-hexane ring is almost normal to the benzene ring and the mean plane of the 1,2,4-thia-diazinane ring, making dihedral angles of 70.4 (2) and 71.43 (19...
متن کاملcatena-Poly[[aqua(dipyrido[3,2-a:2′,3′-c]phenazine-κ2 N 4,N 5)zinc(II)]-μ-pyrazine-2,3-dicarboxylato-κ3 N 1,O 2:O 3]
In the title compound, [Zn(C(6)H(2)N(2)O(4))(C(18)H(10)N(4))(H(2)O)](n) or [Zn(PZDC)(DPPZ)(H(2)O)](n) (where DPPZ is dipyrido[3,2-a:2',3'-c]phenazine and H(2)PZDC is pyrazine-2,3-dicarboxylic acid), the Zn atom is six-coordinated in a slightly distorted octa-hedral coordination geometry by three N atoms from one DPPZ ligand and one PZDC(2-) dianion, three O atoms from two different PZDC(2-) lig...
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013