1-(3-Chlorophenyl)thiourea
نویسندگان
چکیده
In the title compound, C(7)H(7)ClN(2)S, the thio-urea N-C(=S)-N plane forms a dihedral angle of 64.80 (6)° with the benzene ring. In the crystal, mol-ecules are linked via inter-molecular N-H⋯S and N-H⋯Cl hydrogen bonds into a sheet extending parallel to the (101) plane.
منابع مشابه
1-(4-Chlorophenyl)-3-(2-thienylcarbonyl)thiourea
The title compound, C(12)H(9)ClN(2)OS(2), exists in the thio-amide form with an intra-molecular N-H⋯O hydrogen bond across the thio-urea and the carbonyl group. The dihedral angle between the rings is 10.36 (11)°. In the crystal structure, mol-ecules are linked into chains by weak inter-molecular C-H⋯Cl hydrogen-bonding inter-actions.
متن کامل3-Acetyl-1-(3-chlorophenyl)thiourea
In the title compound, C(9)H(9)ClN(2)OS, the 3-chloro-phenyl and acetyl-thio-urea fragments are oriented at a dihedral angle of 62.68 (5)°. An intra-molecular N-H⋯O hydrogen bond generates an S(6) ring motif. Mol-ecules are linked into dimers via a cyclic R(2) (2)(8) motif of N-H⋯S hydrogen bonds. These dimers are further connected through C-H⋯S inter-actions, completing an R(2) (2)(12) motif, ...
متن کامل1-(4-Chlorobutanoyl)-3-(3-chlorophenyl)thiourea
The two independent mol-ecules in the asymmetric unit of the title compound, C11H12Cl2N2OS, exhibit different conformations, with the benzene ring and the N2CS thio-urea group forming dihedral angles of 87.40 (18) and 69.42 (15)°. An intra-molecular N-H⋯O hydrogen bond is present in each mol-ecule. Two further N-H⋯O hydrogen bonds link the independent mol-ecules into a dimer. In the crystal, th...
متن کامل1-(4-Chlorophenyl)-3-(2,4-dichlorobenzoyl)thiourea
The title compound, C(14)H(9)Cl(3)N(2)OS, has bond lengths and angles which are quite typical for thio-urea compounds of this class. The mol-ecule exists in the solid state in its thione form with typical thio-urea C=S and C=O bond lengths, as well as shortened C-N bonds. An intra-molecular N-H⋯O hydrogen bond stabilizes the mol-ecular conformation. Inter-molecular N-H⋯S hydrogen bonds link the...
متن کامل1-(4-Chlorobutanoyl)-3-(2-chlorophenyl)thiourea
The asymmetric unit of the title compound, C(11)H(12)Cl(2)N(2)OS, contains two crystallographically independent mol-ecules with different conformations: the benzene ring and the thio-urea fragment form dihedral angles of 74.32 (11) and 89.39 (11)°. One amino group in each mol-ecule is involved in intra-molecular N-H⋯O and inter-molecular N-H⋯O hydrogen bonding: the latter links pairs of indepen...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012