Low temperature synthesis and characterization of lanthanide-doped BaTiO3 nanocrystals.

نویسندگان

  • Sean P Culver
  • Viktor Stepanov
  • Matthew Mecklenburg
  • Susumu Takahashi
  • Richard L Brutchey
چکیده

The vapor diffusion sol-gel (VDSG) method was employed for the room-temperature synthesis of ~10 nm, aliovalently doped 0.4, 0.8, and 1.6 mol% La:BaTiO3 and 0.4, 0.6, and 1.2 mol% Dy:BaTiO3 nanocrystals. Maximum ensemble relative permittivities of 176 and 208 were observed in the 0.8 mol% La:BaTiO3 and the 1.2 mol% Dy:BaTiO3 nanocrystals, respectively, relative to 89 for undoped BaTiO3 (at 1 MHz, 25 °C) due to local disorder induced by aliovalent substitution.

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عنوان ژورنال:
  • Chemical communications

دوره 50 26  شماره 

صفحات  -

تاریخ انتشار 2014