1-[(Ferrocen-1-yl)methyl]-3-(naphthalen-1-yl)thiourea
نویسندگان
چکیده
In the title compound, [Fe(C(5)H(5))(C(17)H(15)N(2)S)], the cyclo-penta-dienyl (Cp) rings are almost parallel and essentially eclipsed, with a dihedral angle between the Cp ring planes of 0.807 (11)°. The Fe atom is slightly closer to the substituted cyclo-penta-dienyl ring, with an Fe-centroid distance of 1.6510 (8) Å, compared with 1.6597 (8) Å for the unsubstituted ring. The bridging unit between the substituted Cp ring and the naphthyl ring system is planar within 0.0174 Å and makes dihedral angles of 59.032 (10) and 66.02 (2)°, respectively, with these two rings. The angle between the substituted Cp ring and the naphthyl ring system is 72.094 (18)°. The H atoms of the NH groups of the thio-urea moiety are positioned anti with respect to each other. In the crystal, mol-ecules form centrosymmetric dimers via pairs of N-H⋯S hydrogen bonds.
منابع مشابه
1-[(3-Methylpiperidin-1-yl)(3-nitrophenyl)methyl]naphthalen-2-ol
The title compound, C(23)H(24)N(2)O(3), was synthesized from naphthalen-2-ol, 3-nitro-benzaldehyde and 3-methyl-piperidine. The dihedral angles between the naphthalene system and the nitro-benzene and methyl-piperidine rings are 78.53 (13) and 64.14 (15)°, respectively. The mol-ecular conformation is stabilized by a strong intra-molecular O-H⋯N hydrogen bond.
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Individual ions and the solvating water mol-ecule constituting the structure of the title compound, [Fe(C8H13N)(C17H14P)]Cl·H2O, assemble into dimeric units located around crystallographic inversion centers via N-H⋯Cl and O-H⋯Cl hydrogen bonds. These discrete fragments are further inter-connected into chains by C-H⋯O inter-actions. The disubstituted ferrocene core in the {[1'-(di-phenyl-phosphi...
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