An unprecedented Fe(III)(mu-OH)Zn(II) complex that mimics the structural and functional properties of purple acid phosphatases.
نویسندگان
چکیده
FeIII(μ-OH)ZnII Complex that Mimics the Structural and Functional Properties of Purple Acid Phosphatases Ademir Neves,*,† Mauricio Lanznaster,† Adailton J. Bortoluzzi,† Rosely A. Peralta,† Annelise Casellato,†,§ Eduardo Ernesto Castellano,‡ Paul Herrald,§ Mark J. Riley,§ and Gerhard Schenk§ LABINC, Departamento de Quı́mica, UniVersidade Federal de Santa Catarina, 88040-900 Florianópolis, SC, Brazil, Instituto de Fı́sica, UniVersidade de São Paulo, 13560-970 São Carlos, SP, Brazil, and School of Molecular and Microbial Sciences, The UniVersity of Queensland, St. Lucia, QLD 4072, Australia
منابع مشابه
Synthesis and characterization of the tetranuclear iron(III) complex of a new asymmetric multidentate ligand. A structural model for purple acid phosphatases.
The ligand, 2-((2-hydroxy-5-methyl-3-((pyridin-2-ylmethylamino)methyl)benzyl)(2-hydroxybenzyl)amino)acetic acid (H(3)HPBA), which contains a donor atom set that mimics that of the active site of purple acid phosphatase is described. Reaction of H(3)HPBA with iron(III) or iron(II) salts results in formation of the tetranuclear complex, [Fe(4)(HPBA)(2)(OAc)(2)(mu-O)(mu-OH)(OH(2))(2)]ClO(4) x 5H(2...
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 129 24 شماره
صفحات -
تاریخ انتشار 2007