Large-scale synthesis of highly dispersed layered double hydroxide powders containing delaminated single layer nanosheets.
نویسندگان
چکیده
A facile method for the synthesis of Zn2Al-borate and Mg3Al-borate layered double hydroxides (LDHs) with extremely high specific surface areas of 458.6 and 263 m(2) g(-1) and containing delaminated nanosheets is reported. To the best of our knowledge, this is the first report of LDH powders that still remain exfoliated on drying.
منابع مشابه
One-step direct synthesis of layered double hydroxide single-layer nanosheets.
Layered double hydroxide (LDH) single-layer nanosheets were traditionally prepared through a multi-step exfoliation process which is very time-consuming and of low efficiency. Herein we report the preparation of LDH single-layer nanosheets through a facile direct synthesis method. By introducing a layer growth inhibitor, one can directly synthesize LDH single-layer nanosheets instead of LDH lay...
متن کاملElectrochemical performance of cobalt hydroxide nanosheets formed by the delamination of layered cobalt hydroxide in water.
We report the preparation of monometallic Co(2+)/Co(3+) layered double hydroxide, intercalated with lactate anions (LCoH-Lactate), and its spontaneous delamination in water to form cobalt hydroxide nanosheets. These hydroxide nanosheets formed stable aqueous dispersions. The thickness of a nanosheet was estimated to be approximately 1 nm by atomic force microscopy and small angle X-ray scatteri...
متن کاملSynthesis of graphene nanosheets with good control over the number of layers within the two-dimensional galleries of layered double hydroxides.
Graphene nanosheets have been generated in the confined space of the two-dimensional galleries of a layered double hydroxide (LDH) and good control over the number of graphene layers can be achieved by adjusting the amounts of intercalated carbon source.
متن کاملFabrication of Naphthol green B/layered double hydroxide nanosheets ultrathin film and its application in electrocatalysis
A facile enzyme-free hydrogenperoxide electrochemical sensorwas fabricated based onmultilayer ultrathin film containing Naphthol green B anions (NGB) and exfoliated nanosheets of Co–Al layered double hydroxide (LDH) via layer-by-layer self-assembly technique. The X-ray diffraction pattern indicates the superlattice structure of the filmwith repeating distance of 4.15nm; SEM and AFM images show ...
متن کاملStructural characterisation of a layered double hydroxide nanosheet.
We report the atomic-scale structure of a Zn₁₅₂Al-borate layered double hydroxide (LDH) nanosheet, as determined by reverse Monte Carlo (RMC) modelling of X-ray total scattering data. This study involves the extension of the RMC method to enable structural refinement of two-dimensional nanomaterials. The refined LDH models show the intra-layer geometry in this highly-exfoliated phase to be cons...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 49 56 شماره
صفحات -
تاریخ انتشار 2013