Lewis acid/CpRu dual catalysis in the enantioselective decarboxylative allylation of ketone enolates.
نویسندگان
چکیده
The addition of a Lewis acidic metal triflate salt Mg(OTf)(2) as co-catalyst in the CpRu-catalyzed decarboxylative allylation of in situ-generated ketone enolates allows the reaction to proceed at lower temperature with higher regio- and enantioselectivity. Even so-far-unreactive substrates react.
منابع مشابه
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 7 19 شماره
صفحات -
تاریخ انتشار 2009