Direct observation of a carbonylation reaction relevant to CO/alkene copolymerization in a methylpalladium carbonyl complex containing a bis(N-heterocyclic carbene) ligand.
نویسندگان
چکیده
Use of a bulky bidentate bis(NHC) ligand allows isolation of a stable cationic methylpalladium carbonyl complex that undergoes clean carbonylation to an acyl complex under excess CO, modeling a key step in CO/alkene copolymerization.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 35 شماره
صفحات -
تاریخ انتشار 2009