On the basicity of hydroxylamine and its derivatives
نویسنده
چکیده
The рКа. values of hydroxylamine and its derivatives were determined titrimetrically in water and water — ethanol mixtures. The obtained püCa values of the O-alkylhydroxylamines were correlated with the half-wave potentials of the Polarographie reduction waves. A surprisingly high pi£a value of hydroxylamine was explained on the basis of the formation of hydrogen bonds with solvent proved by means of infrared spectra.
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