High pressure X-ray diffraction study of potassium azide

نویسندگان

  • Cheng Ji
  • Fuxiang Zhang
  • Dongbin Hou
  • Hongyang Zhu
  • Jianzhe Wu
  • Ming-Chien Chyu
  • Valery I. Levitas
  • Yanzhang Ma
چکیده

Crystal structure and compressibility of potassium azide was investigated by in-situ synchrotron powder X-ray diffraction in a diamond anvil cell at room temperature up to 37.7 GPa. In the bodycentered tetragonal (bct) phase, an anisotropic compressibility was observed with greater compressibility in the direction perpendicular to the plane containing N3 ions than directions within that plane. The bulk modulus of the bct phase was determined to be 18.6(7) GPa. A pressure-induced phase transition may occur at 15.5 GPa. & 2011 Elsevier Ltd. All rights reserved.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

نرم شدگی فونون‌های انرژی بالا با گذار عایق - ابررسانا در سیستم ابررسانای Ba1-xKxBiO3

Single crystals of Ba1-xKxBiO3 compound for 0 < x <0.6 from insulator to superconducting region have been grown by electrochemical method. The crystals have been characterized by powder x-ray diffraction and Laue x-ray to determine the crystal structure, formed phases and potassium concentration. Inelastic x-ray scattering spectrum of the crystals has been studied to investigate the phonon pro...

متن کامل

High Pressure-High Temperature, X-Ray Diffraction Apparatus

A tetrahedral-anvil press has been developed that permits x-ray diffraction powder measurements at pressures to 75 kb and temperatures to 1000°C. A counting technique, rather than photographic film, is used for x-ray detection. Sample tetrahedra of compressed LiH, boron, and boron-filled plastic are used in place of the pyrophyllite customarily used for this purpose. Two possible entrance pupil...

متن کامل

Structural changes in liquid Fe at high pressures and high temperatures from Synchrotron X-ray Diffraction

– High-energy synchrotron X-ray diffraction measurements on liquid iron in the vicinity of the δ-γ-liquid triple point (to 2300 K and 5 GPa) reveal significant changes in the structure of the liquid upon increasing pressure and temperature. The second and third neighbor shells in the g(r) shift to shorter distances and develop new structure with increasing pressure. The results can be interpret...

متن کامل

Potassium 1,1'-dinitramino-5,5'-bistetrazolate: a primary explosive with fast detonation and high initiation power.

Adequate primary explosives such as lead azide mostly contain toxic ingredients, which have to be replaced. A new candidate that shows high potential, potassium 1,1'-dinitramino-5,5'-bistetrazolate (K2DNABT), was synthesized by a sophisticated synthetic procedure based on dimethylcarbonate and glyoxal. It was intensively characterized for its chemical (X-ray diffraction, EA, NMR and vibrational...

متن کامل

A comparison study on corrosion behavior of zinc phosphate and potassium zinc phosphate anticorrosive pigments

In this article, the effect of potassium on structure and anticorrosion properties of zinc phosphate pigments has been investigated. The co-precipitation method was selected as synthesis method of potassium zinc phosphate pigment. Then the synthesized pigment was characterized by x-ray diffraction XRD, Fourier transform infrared FTIR and Raman spectroscopy. Morphology of the powders was investi...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2011