Organised chaos: entropy in hybrid inorganic–organic systems and other materials
نویسندگان
چکیده
Entropy is one of the fundamental quantities which links emerging research areas like flexibility and defect engineering in inorganic-organic hybrid materials. Additionally, a delicate balance between entropy and enthalpy can lead to intriguing temperature-driven transitions in such materials. Here, we briefly overview traditional material design principles, highlight the role of entropy in the past and discuss how computational methods can help us to understand and quantify entropic effects in inorganic-organic hybrid materials in the future.
منابع مشابه
Modification of mesoporous silica SBA-15 with different organic molecules to gain chemical sensors: a review
The recognition of the biologically and environmentally important ions is of great interest in the field of chemical sensors in recent years. The fluorescent sensors as a powerful optical analytical technique for the detection of low level of various analytes such as anions and metal cations have been progressively developed due to the simplicity, cost effective, and selectivity for monitoring ...
متن کاملIntroduction, synthesis procedures, and applications of organic-inorganic hybrid nanoflowers in biosciences
Organic-inorganic hybrid nanoflowers with flower-like morphology are new nanostructures comprising organic and inorganic components. In general, the organic component of hybrid nanoflowers mostly consists of proteins, DNA, RNA, plant extracts, metabolites, and natural polymers; and the inorganic component composes of various metal phosphates, including copper, calcium, manganese, iron, zinc, co...
متن کاملApplications of hybrid organic–inorganic nanocomposites
Organic–inorganic hybrid materials do not represent only a creative alternative to design new materials and compounds for academic research, but their improved or unusual features allow the development of innovative industrial applications. Nowadays, most of the hybrid materials that have already entered the market are synthesised and processed by using conventional soft chemistry based routes ...
متن کاملNovel application of hybrid Perovskite materials in grid-connected photo-voltaic cells
In this paper, the novel application of organic/inorganic perovskite hybrid materials isproposed for grid-connected Photo-voltaic (PV) cells. The perovskite hybrid cells attracted a lot of interest due to their potential in combining advantages of both components. Looking to the future, there is no doubt that these new generations of hybrid materials, born from the very fruitful activitie...
متن کاملInteraction of Prolin, Leucine and methylurea with inorganic cluster [(PO4)M12O36].nH2O; (M = Mo, W)
Three new inorganic-organic hybrid materials based on heteropolyoxometalates, [L-C6H14NO2]3[(PO4)Mo12O36].3H2O (1), [L-C5H10NO2]3[(PO4)W12O36].H2O (2), and [C2H7N2O]3[(PO4)W12O36]. 4H2O (3), where C6H14NO2, C5H10NO2, and C2H7N2O are protonated L-leucine, L-proline, and methylurea, respectively, have been synthesized and structurally characterized by some physico-chemical methods. Elemental anal...
متن کامل