Facile Oxy-Functionalization of a Nucleophilic Metal Alkyl with a cis-Dioxo Metal Species via a (2+3) Transition StateWe acknowledge the NSF (CHE-0328121) and Chevron Company for financial support. Special thanks to William[emsp14]J. Tenn[emsp14]III, Tim Stewart, and Kenny Young
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چکیده
Selective, low-temperature hydroxylation of alkanes catalyzed by transition-metal complexes is an important area of study, given its possible applications to natural-gas conversion as well as to more efficient production of bulk chemicals and energy. Several promising electrophilic catalysts that couple C–H activation to facile oxy-functionalization of the resulting electrophilically activated M R intermediates have been reported (Figure 1). To address practical challenges with
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