Speciation of heptavalent technetium in sulfuric acid: structural and spectroscopic studies.

نویسندگان

  • Frederic Poineau
  • Philippe F Weck
  • Konstantin German
  • Alesya Maruk
  • Gayane Kirakosyan
  • Wayne Lukens
  • Daniel B Rego
  • Alfred P Sattelberger
  • Kenneth R Czerwinski
چکیده

The speciation of Tc(vii) was studied in 12 M H(2)SO(4) by NMR, UV-visible and XAFS spectroscopy. Experimental results and density functional calculations show the formation of TcO(3)(OH)(H(2)O)(2).

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عنوان ژورنال:
  • Dalton transactions

دوره 39 37  شماره 

صفحات  -

تاریخ انتشار 2010