Relationship Dynamic Viscosity and Inverse Absolute Temperature to the Concentrated Solutions
نویسنده
چکیده
This paper presets the study of the rheological characteristics of the concentrated polyethylene-polypropylene copolymer solutions over the temperature range of 313-363 K and for shear rates between 3 and 1312 s-1. The measurements were performed on a Haake VT 550 rotational rheometer with a HV1 sensor. The rheology of the concentrated solutions is influenced by the shear rate, temperature and concentration of the tested copolymer. We have used a successful model that describes the rheological behaviour of the concentrated solutions in comparison to other models that do not consider the copolymer’s concentration. The parameter A reaches a peak for the 10% solution and a minimum for the 3% solution. The parameter B displays close values for all of the studied solutions.
منابع مشابه
Modeling the Transport and Volumetric Properties of Solutions Containing Polymer and Electrolyte with New Model
A new theoretical model based on the local composition concept (TNRF-mNRTL model) was proposed to express the short-range contribution of the excess Gibbs energy for the solutions containing polymer and electrolyte. This contribution of interaction along with the long-range contribution of interaction (Pitzer-Debye-Hückel equation), configurational entropy of mixing (Flory-Huggins relation)...
متن کاملSimultaneous inversion of mantle properties and initial conditions using an adjoint of mantle convection
[1] Through the assimilation of present-day mantle seismic structure, adjoint methods can be used to constrain the structure of the mantle at earlier times, i.e., mantle initial conditions. However, the application to geophysical problems is restricted through both the high computational expense from repeated iteration between forward and adjoint models and the need to know mantle properties (s...
متن کاملRheological Behaviors of Polyacrylonitrile/1-Butyl-3-Methylimidazolium Chloride Concentrated Solutions
One of the room temperature ionic liquids (RTILs), 1-butyl-3-methylimidazolium chloride ([BMIM]Cl) was chosen to prepare the concentrated solutions of Polyacrylonitrile (PAN). The rheological behaviors of the solutions were measured with rotational rheometry under different conditions, including temperatures, concentration, and molecular weight of PAN. The solutions exhibited shear-thinning beh...
متن کاملExperimental measurement of dynamic viscosity of CeO2-EG at different concentrations and temperatures and proposing a new correlation
Nanofluid is prepared through the nanoscale particles suspended in a fluid base and Nanotechnology is a new attempt to investigate the thermal sciences. As a result of huge investment in developed countries on nanotechnology, research on thermal properties of nano-fluids is of particular interest.Due to the usage of nanotechnology to reduce energy waste, in this project CeO2 with EG is used to ...
متن کاملAdaptation of a High-Pressure Liquid Chromatography System for the Measurement of Viscosity
The state-of-the-art instruments for the determination of viscosity of liquids typically require a significant amount of sample, and have relatively low throughput due to manual and sequential measurements. In this study, it was demonstrated that the pressure generated by the flow of viscous fluids through a capillary could be precisely measured employing high-pressure liquid chromatography sys...
متن کامل