A coordination polymer of CdII with benzene-1,3-dicarboxylate and 1,4-bis[1-(2-pyridylmethyl)benzimidazol-2-yl]butane
نویسندگان
چکیده
The title Cd(II) coordination polymer, catena-poly[[{1,4-bis-[1-(2-pyridylmeth-yl)benzimidazol-2-yl]butane}cadmium(II)]-μ-benzene-1,3-dicarboxyl-ato], [Cd(C(8)H(4)O(4))(C(30)H(28)N(6))](n), was obtained by reaction of CdCO(3), benzene-1,3-dicarboxylic acid (H(2)btc) and 1,4-bis-[1-(2-pyridylmeth-yl)benzimidazol-2-yl]butane (L). The Cd(II) cation is six-coordinated by an N(2)O(4)-donor set. L acts as a bidentate ligand and btc anions link Cd(II) centers into a chain propagating parallel to [010].
منابع مشابه
Poly[bis[chloridocopper(I)]-μ4-1,4-bis[1-(3-pyridylmethyl)-1H-benzimidazol-2-yl]butane]
The title Cu(I) coordination polymer, [Cu(2)Cl(2)(C(30)H(28)N(6))](n), was obtained by reaction of CuCl(2)·2H(2)O and 1,4-bis-[1-(3-pyridyl-meth-yl)-1H-benzimidazol-2-yl]butane. Each Cu(I) cation is three-coordinated by a ClN(2) donor set. The anion acts as a tetra-dentate ligand, linking Cu(I) centres into a polymeric chain.
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