5,6-Dioxo-1,10-phenanthrolin-1-ium nitrate
نویسندگان
چکیده
In the title salt, C(12)H(7)N(2)O(2) (+)·NO(3) (-), the monoprotonated cation is connected to the nitrate anion by a hydrogen bond. Weak C-H⋯O hydrogen bonds hold the planar cations together in a layer structure.
منابع مشابه
5,6-Dioxo-1,10-phenanthrolin-1-ium chloride
The title compound, C(12)H(7)N(2)O(2) (+)·Cl(-), is isostructural with its bromide analogue. The compound exhibits a layered structure in which all atoms lie on a crystallographic mirror plane. N(+)-H⋯Cl(-) hydrogen bonds, C-H⋯O and C-H⋯Cl(-) contacts are formed within each layer. The perpendicular separation between the layers is 3.141 (1) Å.
متن کامل1,10-Phenanthrolin-1-ium nitrate–aquabis(4-hydroxybenzoato-κ2 O,O′)(nitrato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)erbium(III)–1,10-phenanthroline–water (1/1/0.5/2)
In the title compound, C(12)H(9)N(2) (+)·NO(3) (-)·[Er(C(7)H(5)O(3))(2)(NO(3))(C(12)H(8)N(2))(H(2)O)]·0.5C(12)H(8)N(2)·2H(2)O, the water-mol-ecule-coordinated Er(III) ion is chelated by one 1,10-phenanthroline (phen) ligand, two 4-hy-droxy-benzoate anions and one nitrate anion in a monocapped square-anti-prismatic coordination geometry. The uncoordinating phen mol-ecule is approximately paralle...
متن کامل5,6-Dihydroxy-1,10-phenanthrolin-1-ium chloride dihydrate
The title compound, C(12)H(9)N(2)O(2) (+)·Cl(-)·2H(2)O, exhibits a layered structure which is stabilized by inter-molecular O-H⋯O, O-H⋯Cl(-) and N(+)-H⋯Cl(-) hydrogen bonds, and π-π inter-actions (centroid-centroid distances = 3.654 and 3.583 Å). The distances between the molecules are 3.371 and 3.294 Å.
متن کامل3,4,7,8-Tetramethyl-1,10-phenanthrolin-1-ium nitrate monohydrate
In the crystal of the title compound, C(16)H(17)N(2) (+)·NO(3) (-)·H(2)O, the tetra-methyl-1,10-phenanthrolinium cations, nitrate anions and lattice water mol-ecules are all located on a mirror plane with the methyl H atoms of the cation equally disordered over two sites about the mirror plane. The cation, anion and water mol-ecule are linked by O-H⋯O and N-H⋯O hydrogen bonds into a sheet paral...
متن کامل2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate
In the title compound, (C₁₄H₁₃N₂)[FeCl₄]·CH₃OH, the 2,9-dimethyl-1,10-phenanthrolin-1-ium cation, FeCl₄ ⁻ anion and methanol solvent mol-ecule lie on a twofold rotation axis. Due to symmetry, the H atom on the N atom of the cation is half-occupied. In the anion, the Fe(III) atom has a tetra-hedral geometry. H atoms of the methanol mol-ecule are disordered over two sets of sites around the twofo...
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