Synthesis and rearrangement of a bridged thioamide.
نویسندگان
چکیده
The synthesis of a bridged thiolactam is described. This thiolactam is shown to undergo an unusual C-N bond cleavage reaction under conditions of its synthesis. Spectroscopic properties of the thiolactam indicate a considerable degree of twist of the thioamide bond.
منابع مشابه
Green and efficient synthesis of propargylamines via A3 coupling reaction using a copper (II)–thioamide combination
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 شماره
صفحات -
تاریخ انتشار 2009