1-(2-Chloro­benzo­yl)-3-(2-trifluoro­methyl­phen­yl)thio­urea

نویسندگان

  • M. Khawar Rauf
  • Masahiro Ebihara
  • Amin Badshah
چکیده

The dihedral angle between the benzene rings in the title compound, C15H10ClF3N2OS, is 54.02 (4)°. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, N-H⋯S hydrogen bonds link the mol-ecules into inversion dimers.

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منابع مشابه

1-(2-Chloro­benzo­yl)-3-(2,3-dimethyl­phen­yl)thio­urea

The dihedral angle between the two phenyl groups in the title compound, C16H15ClN2OS, is 14.88 (4)°. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, pairs of N-H⋯S hydrogen bonds link the mol-ecules into centrosymmetric dimers.

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1-(2-Chloro­benzo­yl)-3-(3-meth­oxy­phen­yl)thio­urea

The title compound, C15H13ClN2O2S, exists in the solid state in its thione form with typical thio-urea C-S and C-O bonds lengths as well as shortened C-N bonds. An intra-molecular N-H⋯O hydrogen bond stabilizes the mol-ecular conformation. In the crystal, N-H⋯S hydrogen bonds link the mol-ecules into centrosymmetric dimers.

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1-(1,3-Benzothia­zol-2-yl)-3-(4-chloro­benzo­yl)thio­urea

The title compound, C(15)H(10)ClN(3)OS(2), adopts a cis-trans configuration across the thio-urea C-N bonds with respect to the positions of the benzothia-zole and 4-chloro-benzoyl groups relative to thiono S atom. An intra-molecular N-H⋯O hydrogen bond is present. In the crystal structure, mol-ecules are linked by a weak inter-molecular N-H⋯S hydrogen bond, forming centrosymmetric dimers.

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N-(4-Chloro­benzo­yl)-N′-(3-fluoro­phen­yl)thio­urea

In the title compound, C(14)H(10)ClFN(2)OS, the mol-ecule adopts a trans-cis geometry of the thio-urea unit. The dihedral angles between the benzene rings is 34.47 (7)°. The crystal packing features inter-molecular N-H⋯S and C-H⋯O hydrogen bonds, forming a chain along the b axis. A short C-H⋯S intramolecular contact is also observed.

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عنوان ژورنال:

دوره 69  شماره 

صفحات  -

تاریخ انتشار 2013