Water-exchange rates of lanthanide ions in an ionic liquid.
نویسندگان
چکیده
The first ligand-exchange rate measurements of lanthanide ions in an ionic liquid are reported here. The trend of water-exchange rates in the ionic liquid is the opposite of the trend in water.
منابع مشابه
Simulations of the water exchange dynamics of lanthanide ions in 1-ethyl-3-methylimidazolium ethyl sulfate ([EMIm][EtSO4]) and water.
The dynamics of ligand exchange on lanthanide ions is important for catalysis and organic reactions. Recent 17O-NMR experiments have shown that water-exchange rates of lanthanide ions in water/1-ethyl-3-methylimidazolium ethyl sulfate (water/[EMIm][EtSO4]) increase as a function of increasing charge density. The trend of water-exchange rates in this solvent is opposite to that observed in water...
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ورودعنوان ژورنال:
- Dalton transactions
دوره 43 43 شماره
صفحات -
تاریخ انتشار 2014