Synthesis and characterization of [Fe(BPMEN)ACC]SbF₆: a structural and functional mimic of ACC-oxidase.

نویسندگان

  • Y Roux
  • W Ghattas
  • F Avenier
  • R Guillot
  • A J Simaan
  • J-P Mahy
چکیده

A mononuclear Fe(II) complex bearing 1-aminocyclopropane-1-carboxylic acid (ACCH) was synthesized and characterized. X-ray crystallography demonstrated that ACC binds to the Fe(II) ion in a bidentate mode constituting the first structural mimic of the expected binding of ACC to the Fe(II) center of the ethylene forming enzyme ACC-oxidase (ACCO). [Fe(BPMEN)ACC]SbF6 also constitutes a functional biomimetic complex of ACCO, as it reacts with hydrogen peroxide producing ethylene.

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عنوان ژورنال:
  • Dalton transactions

دوره 44 13  شماره 

صفحات  -

تاریخ انتشار 2015