4,4′-Bis(1,2,4-triazol-1-ylmethyl)biphenyl
نویسنده
چکیده
In the title compound, C(18)H(16)N(6), the complete mol-ecule is generated by crystallographic inversion symmetry. The dihedral angle between the benzene and triazole rings is 84.1 (3)°. The crystal structure is stabilized by weak C-H⋯N hydrogen bonds.
منابع مشابه
A two-dimensional Zn coordination polymer with a three-dimensional supramolecular architecture
The title compound, poly[bis-{μ2-4,4'-bis-[(1,2,4-triazol-1-yl)meth-yl]biphenyl-κ2N4:N4'}bis-(nitrato-κO)zinc(II)], [Zn(NO3)2(C18H16N6)2] n , is a two-dimensional zinc coordination polymer constructed from 4,4'-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]-1,1'-biphenyl units. It was synthesized and characterized by elemental analysis and single-crystal X-ray diffraction. The ZnII cation is located on a...
متن کامل[μ-1,4-Bis(1,2,4-triazol-1-ylmethyl)benzene]bis[aqua(pyridine-2,6-dicarboxylato)copper(II)] monohydrate
The title compound, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(12)N(6))(H(2)O)(2)]·H(2)O, displays a discrete dinuclear structure, in which the central Cu(II) atom is five-coordinated in a distorted square-based pyramidal coordination geometry and the flexible ligand 1,4-bis-(1,2,4-triazol-1-ylmeth-yl)benzene adopts a bis-monodentate bridging mode linking the Cu(II) atoms. It is further assembled by O-H⋯O...
متن کاملcatena-Poly[[[tetraaquazinc(II)]-μ-1,4-bis(1,2,4-triazol-1-yl)butane-κ2 N 4:N 4′] biphenyl-4,4′-dicarboxylate]
The asymmetric unit of the polymeric title compound, {[Zn(C(8)H(12)N(6))(H(2)O)(4)](C(14)H(8)O(4))}(n) or {[Zn(BTB)(H(2)O)(4)](BPDC)}(n) [BTB is 1,4-bis-(1,2,4-triazol-1-yl)butane and H(2)BPDC is biphenyl-4,4'-dicarb-oxy-lic acid], contains half a [Zn(BTB)(H(2)O)(4)](2+) cation and half a BPDC anion, both ions lying about a crystallographic inversion centre. The crystal structure consists of zi...
متن کاملPoly[bis[μ2-1,4-bis(1,2,4-triazol-1-ylmethyl)benzene-κ2 N 4:N 4′]bis(nitrito-κO)cobalt(II)]
The Co(II) atom in the title complex, [Co(NO(2))(2)(C(12)H(12)N(6))(2)](n), lies on an inversion center and is coordinated by four N atoms from the triazole rings of two symmetry-related pairs of 1,4-bis-(1,2,4-triazol-1-ylmeth-yl)benzene (bbtz) ligands and two O atoms from two symmetry-related monodentate nitrate ligands in a distorted octa-hedral geometry. The Co atoms are bridged by four bbt...
متن کاملSynthesis, Crystal Structure and Luminescent Properties of 2D Zinc Coordination Polymers Based on Bis(1,2,4-triazol-1-yl)methane and 1,3-Bis(1,2,4-triazol-1-yl)propane
Two new two-dimensional zinc(II) coordination polymers containing 2,5thiophenedicarboxylate and bitopic ligands bis(1,2,4-triazol-1-yl)methane (btrm) or 1,3-bis (1,2,4-triazol-1-yl)propane (btrp) were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction, and thermal analysis. Crystal structures of coordination polymers were deter...
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