Platinum-catalyzed cross-dehydrogenative coupling reaction in the absence of oxidant.

نویسندگان

  • Xing-Zhong Shu
  • Yan-Fang Yang
  • Xiao-Feng Xia
  • Ke-Gong Ji
  • Xue-Yuan Liu
  • Yong-Min Liang
چکیده

A third strategy for cross-dehydrogenative coupling reaction has been reported via platinum-catalyzed sp(3) C-H and sp(3) C-H coupling reaction in the absence of oxidant. Nitroalkanes as well as dialkyl malonate derivatives, beta-keto esters and malononitrile are active participants in this coupling reaction. Both cyclic and acyclic non-activated simple ketones are good reactants in this reaction.

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عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 8 18  شماره 

صفحات  -

تاریخ انتشار 2010