Bis(2-methylpiperidinium) pentachloridoantimonate(III)
نویسنده
چکیده
The asymmetric unit of the title compound, (C(6)H(14)N)(2)[SbCl(5)], contains one cation and half of the anion on a special position (specifically, the Sb(III) ion and three chloride anions are situated on a mirror plane). In the [SbCl(5)](2-) unit, the Sb(III) ion is coordinated by five chloride anions [Sb-Cl = 2.3721 (11)-2.6656 (12) Å] in a distorted square-pyramidal geometry. However, one chloride anion from a neighbouring [SbCl(5)](2-) unit provides a short Sb⋯Cl contact of 3.3600 (12) Å and completes the Sb coordination environment up to an elongated octa-hedron. In the crystal, N-H⋯Cl hydrogen bonds link cations and anions into columns propagating along [100].
منابع مشابه
Bis(3-methylpiperidinium) naphthalene-1,5-disulfonate
The asymmetric unit of the title compound, 2C(6)H(14)N(+)·C(10)H(6)O(6)S(2) (2-), contains one 3-methyl-piperidinium cation and one-half of the centrosymmetric naphthalene-1,5-disulfonate anion. In the crystal, anions and cations are linked through N-H⋯O hydrogen bonds into layers parallel to (101).
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In the structure of the title mol-ecular salt, 2C(6)H(14)N(+)·C(10)H(6)O(6)S(2) (2-), the asymmetric unit consists of one 2-methyl-piperidinium cation and one-half of a naphthalene-1,5-disulfonate anion; the anion lies across a centre of symmetry. In the crystal, the cations and anions are linked through N-H⋯O hydrogen bonds, forming a two-dimensional network.
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The crystal structure of the title compound, (C(6)H(14)N)(2)[SnCl(6)], is built of 4-methyl-piperidinium cations, occupying special positions on the mirror plane, and hexa-chloridostannate(IV) anions on a special position of 2/m symmetry. The ions are linked via N-H⋯Cl hydrogen bonds into chains running along the b axis.
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In the title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl, the Sb(III) cation is coordinated by five Cl(-) anions in a distorted square-pyramidal geometry, in which the longest Sb-Cl distance of 3.0319 (14) Å indicates a weak coordination bond. In the crystal, the 3-methyl-anilinium cations link with the complex antimonate anions and Cl(-) anions via N-H⋯Cl hydrogen bonds.
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