catena-Poly[diquinolinium [[diaquacobaltate(II)]-μ-cyclotetraphosphato] hexahydrate]
نویسندگان
چکیده
The cyclo-tetra-phosphate anion, [P(4)O(12)](4-), forms the title complex with cobalt(II) and quinolinium, {(C(9)H(8)N)(2)[Co(P(4)O(12))(H(2)O)(2)]·6H(2)O}(n). In the complex anion, the Co(II) ion, lying on an inversion center, is surrounded by four phosphate O atoms and two water mol-ecules in a slightly distorted octa-hedral geometry. The crystal structure consists of anionic ribbons of formula {[Co(P(4)O(12))(H(2)O)(2)](2-)}(n) extending along [100]. A network of O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds consolidates the crystal packing.
منابع مشابه
catena-Poly[diammonium [diaquabis(pyridine-2,4-dicarboxylato-κ2 N,O 2)cuprate(II)] [[diaquacopper(II)]-μ-pyridine-2,4-dicarboxylato-κ3 N,O 2:O 2′-[tetraaquacadmium(II)]-μ-pyridine-2,4-dicarboxylato-κ3 O 2:N,O 2′] hexahydrate]
The title mixed-metal complex, {(NH(4))(2)[Cu(C(7)H(3)NO(4))(2)(H(2)O)(2)][CdCu(C(7)H(3)NO(4))(2)(H(2)O)(6)]·6H(2)O}(n), contains one octa-hedrally coordinated Cd(II) center and two octa-hedrally coordinated Cu(II) centers, each lying on an inversion center. The two Cu(II) atoms are each coordinated by two O atoms and two N atoms from two 2,4-pydc (2,4-H(2)pydc = pyridine-2,4-dicarboxylic acid)...
متن کاملcatena-Poly[[[aquamanganese(II)]-di-μ-sulfato-[aquamanganese(II)]-μ-N,N,N′,N′-tetrakis(2-pyridylmethyl)hexane-1,6-diamine] hexahydrate]
In the polymeric title compound, {[Mn(2)(SO(4))(2)(C(30)H(36)N(6))(H(2)O)(2)]·6H(2)O}(n), the two Mn(2+) ions are bridged by two sulfate anions to form dinuclear complexes, and these dinuclear species are linked by the hexa-dentate ligand N,N,N',N'-tetra-kis(2-pyridylmeth-yl)hexane-1,6-diamine (tphn), forming a one-dimensional chain structure running in the [101] direction. The repeat unit of t...
متن کاملcatena-Poly[[bis(dimethylammonium) [cadmate(II)-bis(μ-1,1′:4′,1′′-terphenyl-3,3′′-dicarboxylato)]] dimethylformamide disolvate]
In the title compound, {(C(2)H(8)N)(2)[Cd(C(20)H(12)O(4))(2)]·2C(3)H(7)NO}(n), the Cd(II) ion lies on a twofold rotation axis and is in a distorted octa-hedral CdO(6) environment, defined by four O atoms of two μ(2)-coordinated 1,1':4',1''-terphenyl-3,3''-dicarboxyl-ate (DCT) ligands and two O atoms of two μ(1)-coordinated DCT ligands. Both types of DCT ligands act as bridging, forming a one-di...
متن کاملcatena-Poly[[diiodidocadmium(II)]-μ-4,4′-di-4-pyridyl-2,2′-disulfanediyldipyrimidine]
In the title compound, [CdI(2)(C(18)H(12)N(6)S(2))](n), the 4,4'-di-4-pyridyl-2,2'-disulfanediyldipyrimidine (L) ligand bridges two Cd(II) centers, forming polymeric zigzag chains extending along the b axis. The Cd(II) ions are coordinated by two N atoms from two L ligands and two iodide anions in a distorted tetra-hedral geometry.
متن کاملcatena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)lead(II)]-di-μ-bromido]
In the title compound, [PbBr(2)(C(14)H(12)N(2))](n), the Pb(II) atom lies on a twofold rotation axis. The N-heterocycle-chelated Pb(II) atom exists in a distorted octa-hedral geometry owing to two long Pb⋯Br inter-actions [2.9562 (5) and 3.2594 (5) Å]. These result in a zigzag chain running along the c axis. The lone pair is stereochemically inactive.
متن کامل