Hierarchically porous organic polymers: highly enhanced gas uptake and transport through templated synthesis† †Electronic supplementary information (ESI) available: Complete procedures for the synthesis of hierarchically porous organic polymers and characterization data (gas adsorption–desorption isotherms, pore size distribution graphs, SEM images, and density data). Detailed procedures for propane uptake experiments and calculation of diffusion constants. See DOI: 10.1039/c4sc02502d Click here for additional data file.

Tetraarylborate polymer networks as single-ion conducting solid electrolytes† †Electronic supplementary information (ESI) available: Adsorption isotherms, IR spectra, synthetic procedures, characterization data, equivalent circuit diagrams and additional SEM images. See DOI: 10.1039/c5sc02052b Click here for additional data file.

Tuning fluorocarbon adsorption in new isoreticular porous coordination frameworks for heat transformation applications† †Electronic supplementary information (ESI) available: Experimental section, PXRD patterns, crystallographic tables and characterization details, and X-ray crystallographic files in CIF format. CCDC 1031873 and 1031874. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03985h Click here for additional data file. Click here for additional data file.

Adsorption heat transformation is one of the most energy-efficient technologies, which relies much on the type and performance of the adsorbent–adsorbate pair. Here, we report adsorption behaviors of a typical fluorocarbon R22 (CHClF2) in a new series of isoreticular porous coordination polymers [Zn4O(bpz)2(ldc)], in which the typical Zn4O clusters are connected by hydrophobic 3,30,5,50-tetrame...

Understanding gas capacity, guest selectivity, and diffusion in porous liquids† †Electronic supplementary information (ESI) available: Detailed synthetic procedures, experimental details and measurements (PDF). See DOI: 10.1039/c6sc05196k Click here for additional data file.

Mesoscopic superstructures of flexible porous coordination polymers synthesized via coordination replication† †Electronic supplementary information (ESI) available: Full experimental procedures, powder X-ray diffraction data, thermogravimetric analysis data, adsorption isotherms, scanning electron microscopy data, and additional discussion. See DOI: 10.1039/c5sc02034d Click here for additional data file.

The coordination replication technique is employed for the direct conversion of a macroand mesoporous Cu(OH)2–polyacrylamide composite to three-dimensional superstructures consisting of the flexible porous coordination polymers, Cu2(bdc)2(MeOH)2 and Cu2(bdc)2(bpy) (bdc 2 1⁄4 1,4-benzenedicarboxylate, bpy 1⁄4 4,40-bipyridine). Detailed characterization of the replicated systems reveals that the ...

Solid state organic amine detection in a photochromic porous metal organic framework† †Electronic supplementary information (ESI) available: Experimental procedures and additional supporting data. CCDC 1024270 and 1024271. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03224a Click here for additional data file. Click here for additional data file.