(+)-Chlorido[(1,2,3,4-η;κP 2′)-2′-diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate
نویسندگان
چکیده
In the title complex, [RhCl(C(44)H(32)OP(2))]·CH(3)OH, the Rh(I) ion is coordinated by a naphthyl group of a partially oxidized 2,2'-bis-(diphenyl-phosphan-yl)-1,1'-binaphthyl (BINAP) ligand in a η(4) mode, one P atom of the diphenyl-phosphanyl group and one Cl atom. The P=O group does not inter-act with the Rh(I) ion but accepts an O-H⋯O hydrogen bond from the methanol solvent mol-ecule.
منابع مشابه
{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC 1}[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) toluene monosolvate
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