Multistep soft chemistry method for valence reduction in transition metal oxides with triangular (CdI2-type) layers.

نویسندگان

  • Colin K Blakely
  • Shaun R Bruno
  • Viktor V Poltavets
چکیده

Transition metal (M) oxides with MO2 triangular layers demonstrate a variety of physical properties depending on the metal oxidation states. In the known compounds, metal oxidation states are limited to either 3+ or mixed-valent 3+/4+. A multistep soft chemistry synthetic route for novel phases with M(2+/3+)O2 triangular layers is reported.

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عنوان ژورنال:
  • Chemical communications

دوره 50 21  شماره 

صفحات  -

تاریخ انتشار 2014