Efficient synthesis of cyclopentenones from enynyl acetates via tandem Au(I)-catalyzed 3,3-rearrangement and the Nazarov reaction.

نویسندگان

  • Liming Zhang
  • Shaozhong Wang
چکیده

A highly efficient method for the synthesis of versatile cyclopentenones from readily available enynyl acetates via tandem Au(I)-catalyzed 3,3-rearrangement and the Nazarov reaction is developed. Significant substrate flexibility and excellent control of the double bond position in the cyclopentenone ring render this an attractive method for cyclopentenone synthesis.

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 128 5  شماره 

صفحات  -

تاریخ انتشار 2006