Constructing explicit magnetic analogies for the dynamics of glass forming liquids.
نویسندگان
چکیده
By defining a spatially varying replica overlap parameter for a supercooled liquid referenced to an ensemble of fiducial liquid state configurations, we explicitly construct a constrained replica free energy functional that maps directly onto an Ising Hamiltonian with both random fields and random interactions whose statistics depend on the liquid structure. Renormalization group results for random magnets when combined with these statistics for the Lennard-Jones glass suggest that discontinuous replica symmetry breaking would occur if a liquid with short range interactions could be equilibrated at a sufficiently low temperature where its mean field configurational entropy would vanish, even though the system strictly retains a finite configurational entropy.
منابع مشابه
Gel-forming patchy colloids and network glass formers: Thermodynamic and Dynamic analogies
This article discusses recent attempts to provide a deeper understanding of the thermoreversible ”gel” state of colloidal matter and to unravel the analogies between gels at the colloidal level and gels at the molecular level, commonly known as network-forming strong liquids. The connection between gel-forming patchy colloids and strong liquids is provided by the limited valence of the inter-pa...
متن کاملStructure and dynamics in protic ionic liquids: a combined optical Kerr-effect and dielectric relaxation spectroscopy study.
The structure and dynamics of ionic liquids (ILs) are unusual due to the strong interactions between the ions and counter ions. These microscopic properties determine the bulk transport properties critical to applications of ILs such as advanced fuel cells. The terahertz dynamics and slower relaxations of simple alkylammonium nitrate protic ionic liquids (PILs) are here studied using femtosecon...
متن کامل7 cf ) Impulsive Stimulated Thermal Scattering of Glass - Forming Liquids
Impulsive Stimulated Thermal Scattering is a time domain laser spectroscopy that is applied to studying the relaxation dynamics of liquids in the supercooled temperature regime. Characterizing the relaxation dynamics of supercooled liquids is essential to developing an understanding of the physics of the liquid-glass transition. Mode Coupling Theory is a popular theory that has had some success...
متن کاملAn Overview on Short and Long Time Relaxations in Glass-forming Supercooled Liquids
Density fluctuations in supercooled liquids near the glass transition relax in multiple steps. The short time relaxation is known as β-relaxation and the final long time relaxation is called α-relaxation. It is believed that the long time α-relaxation is a cooperative phenomena associated with a growing length scales, whereas the short-time β-relaxation is often attributed to spatially local pr...
متن کاملStructural origin of fractional Stokes-Einstein relation in glass-forming liquids
In many glass-forming liquids, fractional Stokes-Einstein relation (SER) is observed above the glass transition temperature. However, the origin of such phenomenon remains elusive. Using molecular dynamics simulations, we investigate the break- down of SER and the onset of fractional SER in a model of metallic glass-forming liquid. We find that SER breaks down when the size of the largest clust...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- The Journal of chemical physics
دوره 129 19 شماره
صفحات -
تاریخ انتشار 2008