Prospects for Alkaline Zero Gap Electrolyte Water Electrolysers for Hydrogen Production
نویسندگان
چکیده
This review makes the case for cheaper and more efficient water electrolysis technology. In particular, the potential advantages of zero gap, alkaline water electrolysers based on hydroxide ion conducting membranes are highlighted. Following a brief introduction into the thermodynamics and kinetics of water electrolysis, recent developments in oxygen evolving anodes, hydrogen evolving cathodes and hydroxide transporting membranes appropriate to such technology are reviewed.
منابع مشابه
Nickel based electrocatalysts for oxygen evolution in high current density, alkaline water electrolysers.
A number of nickel based materials are investigated as potential oxygen evolution catalysts under conditions close to those met in modern, high current density alkaline water electrolysers. Microelectrodes are used to avoid distortion of voltammetric data by IR drop even at the high current densities employed in such water electrolysers. High surface area nickel metal oxides prepared by cathodi...
متن کاملEfficient hydrogen production on MoNi4 electrocatalysts with fast water dissociation kinetics
Various platinum-free electrocatalysts have been explored for hydrogen evolution reaction in acidic solutions. However, in economical water-alkali electrolysers, sluggish water dissociation kinetics (Volmer step) on platinum-free electrocatalysts results in poor hydrogen-production activities. Here we report a MoNi4 electrocatalyst supported by MoO2 cuboids on nickel foam (MoNi4/MoO2@Ni), which...
متن کاملSolar water splitting by photovoltaic-electrolysis with a solar-to-hydrogen efficiency over 30%
Hydrogen production via electrochemical water splitting is a promising approach for storing solar energy. For this technology to be economically competitive, it is critical to develop water splitting systems with high solar-to-hydrogen (STH) efficiencies. Here we report a photovoltaic-electrolysis system with the highest STH efficiency for any water splitting technology to date, to the best of ...
متن کاملMaking the hydrogen evolution reaction in polymer electrolyte membrane electrolysers even faster.
Although the hydrogen evolution reaction (HER) is one of the fastest electrocatalytic reactions, modern polymer electrolyte membrane (PEM) electrolysers require larger platinum loadings (∼0.5-1.0 mg cm(-2)) than those in PEM fuel cell anodes and cathodes altogether (∼0.5 mg cm(-2)). Thus, catalyst optimization would help in substantially reducing the costs for hydrogen production using this tec...
متن کاملIn situ activation of a Ni catalyst with Mo ion for hydrogen evolution reaction in alkaline solution
In this study Ni catalyst have been activated during hydrogen evolution reaction (HER) by adding Mo ions into the alkaline electrolyte. After dissolving different amounts of ammonium molybdate in the 1M NaOH as electrolyte, Ni catalyst was used as cathode for HER. Afterwards a comparison between hydrogen overpotential measured in Ni catalyst with and without in situ activation has been made; th...
متن کامل