An atom-economic approach to carboxylic acids via Pd-catalyzed direct addition of formic acid to olefins with acetic anhydride as a co-catalyst.
نویسندگان
چکیده
An effective Pd-catalyzed hydrocarboxylation of olefins using formic acid with acetic anhydride as a co-catalyst is described. A variety of carboxylic acids are obtained in good yields with high regioselectivities under mild reaction conditions without the use of toxic CO gas.
منابع مشابه
Nickel-catalyzed hydrocarboxylation of alkynes with formic acid†
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 13 31 شماره
صفحات -
تاریخ انتشار 2015