{N-[1-(1H-Benzimidazol-2-yl)ethylidene-κN 3]-3-(1H-imidazol-1-yl)propan-1-amine-κN}dibromidomercury(II)
نویسندگان
چکیده
In the title compound, [HgBr(2)(C(15)H(17)N(5))], the Hg(II) ion is tetra-hedrally coordinated by two N atoms of the N-[1-(1H-benzimidazol-2-yl)ethyl-idene-κN]-3-(1H-imidazol-1-yl)propan-1-amine ligand, and two bromide anions. Inter-molecular benzimidazole-imidazole N-H⋯N hydrogen bonds link the mol-ecules into helical chains along the b-axis direction and C-H⋯Br hydrogen bonds link these chains into layers parallel to the bc plane.
منابع مشابه
Diaquabis{3-[4-(1H-imidazol-1-yl)phenyl]-5-(pyridin-2-yl-κN)-1H-1,2,4-triazol-1-ido-κN 1}zinc
The centrosymmetric mol-ecule of the title compound, [Zn(C(16)H(11)N(6))(2)(H(2)O)(2)], contains one Zn(2+) ion located on a center of symmetry, two 3-[4-(1H-imidazol-1-yl)phen-yl]-5-(pyridin-2-yl)-1H-1,2,4-triazol-1-ide (Ippyt) ligands and two coordinating water mol-ecules. The Zn(II) ion is six-coordinated in a distorted octa-hedral coordination geometry by four N atoms from two Ippyt ligands...
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In the centrosymmetric mononuclear title complex, [Ni(NCS)(2)(C(11)H(11)N(3)O)(4)], the Ni(II) atom, located on an inversion centre, is hexa-coordinated in a distorted octa-hedral geometry comprising four N atoms of four monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands and two N atoms from thio-cyanate anions.
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The title compound, [Cu(NCS)(2)(C(11)H(11)N(3)O)(2)], contains two independent Cu(II) atoms. Each Cu(II) atom, lying on an inversion center, is coordinated by two N atoms from two NCS(-) anions and two N atoms from two monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted square-planar geometry. Two S atoms from adjacent mol-ecules occupy the axial positions with lon...
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In the title complex, [Zn(C(10)H(8)N(5))Cl](n), the Zn(II) ion is four-coordinated by one Cl atom and three N atoms from two in situ-generated deprotonated 5-(1-methyl-1H-benzimidazol-2-yl-κN(3))-1,2,3-triazol-1-ide ligands in a slightly distorted tetra-hedral geometry. The Zn(II) ions are bridged by the ligands, forming a helical chain along [001]. C-H⋯N and C-H⋯Cl hydrogen bonds and π-π inter...
متن کاملTetrakis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN 4)propan-1-one]bis(thiocyanato-κN)manganese(II)
In the mononuclear title complex, [Mn(NCS)(2)(C(11)H(11)N(3)O)(4)], the Mn(II) atom, lying on an inversion center, is coordinated by two monodentate thio-cyanate anions and four monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted octa-hedral geometry. Each complex mol-ecule is linked to four neighboring ones by weak C-H⋯N and C-H⋯S hydrogen bonds, forming a two-dim...
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