Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers.

نویسندگان

  • Jered C Garrison
  • Matthew J Panzner
  • Paul D Custer
  • D Venkat Reddy
  • Peter L Rinaldi
  • Claire A Tessier
  • Wiley J Youngs
چکیده

The reaction of 4-ethynyl-pyridine with tert-butyl lithium followed by its addition to (Me3tacn)RhCl3 affords the facial octahedral complex (Me3tacn)Rh(CCPy)3, condensation of which with the square planar complex cis-(DCPE)Pt(NO3)2 results in a self-assembled trigonal bipyramidal cage with Rh(III) and Pt(II) atoms occupying the vertices.

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عنوان ژورنال:
  • Chemical communications

دوره 44  شماره 

صفحات  -

تاریخ انتشار 2006