Simultaneous determination of iron(II) and iron(III) by micellar electrokinetic chromatography using an off-line selective complexing reaction.
نویسندگان
چکیده
A simultaneous determination with UV detection/capillary electrophoresis for Fe(II) and Fe(III) was achieved using a sulfonated bathophenantholine and desfferioxamine B. When the electrophoretic buffer was 60 mmol l(-1) SDS, 10 mmol l(-1) acetic acid (pH 4.0) and 10 mmol l(-1) ascorbic acid and at -10 kV, the iron(II) and iron(III) could not only be completely separated, but also be sensitively determined.
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ورودعنوان ژورنال:
- Analytical sciences : the international journal of the Japan Society for Analytical Chemistry
دوره 19 8 شماره
صفحات -
تاریخ انتشار 2003