Vibronic and spin - orbit coupling of a d ( 9 ) transition - metal

نویسندگان

  • Tohru Sato
  • Arnout Ceulemans
چکیده

Interplay between the vibronic and spin-orbit coupling in the ͑⌫ 8 + ⌫ 9 ͒ ϫ ͑g +2h͒ Jahn-Teller problem, where ⌫ 8 and ⌫ 9 are the quartet and sextet spin representation, and g and h denote the fourfold and fivefold degenerate vibrational modes in icosahedral symmetry, respectively, is studied. A 4d 9 or 5d 9 transition-metal ion in an icosahedral field may provide a realization of this system.

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تاریخ انتشار 2017