Microfabrication through Electrostatic Self-Assembly

We use electrostatic interactions to direct the patterning of gold disks having ∼10-μm diameters on functionalized surfaces. Planar and curved substrates with patterned surface charge were generated either by microcontact printing or by photolithography. Small charged gold disks were generated by electroplating gold into photoresist molds and derivatizing these disks with charged self-assembled monolayers. When agitated as a suspension in contact with the patterned surfaces, the charged gold disks deposited specifically but as disordered aggregates on regions presenting the opposite charge. Positivelycharged disks deposited on phosphonate-, carboxylate-, and SiOH-terminated surfaces but not on trimethylammoniumanddimethylammonium-terminated surfaces, and vice versa for negatively-charged disks. Methyland CF3-terminated surfaces resisted deposition of disks of either charge. Selective and dense assembly was achieved in methanol, ethanol, 2-propanol, and dioxane; in water, deposition was nonspecific. The overlap of disks was eliminated by using disks with ∼1:1 aspect ratios.