The structure of ultrathin Langmuir-Blodgett films of cadmium behenate.

نویسندگان

  • J B Peng
  • G J Foran
  • G T Barnes
  • I R Gentle
چکیده

Grazing incidence x-ray-diffraction investigations of the structures of Langmuir-Blodgett films of cadmium behenate with 1, 2, 3, 5, and 21 monolayers are reported. The single monolayer film, deposited on a hydrophilic substrate, showed a hexagonal structure, whereas the bilayer film, deposited on a hydrophobic substrate, had a rectangular structure with herringbone orientation of the acyl chains. With multilayer films formed on a hydrophilic substrate, it was possible to detect that the hexagonal structure of the first layer was retained when additional layers were deposited and that the additional layers had the same rectangular structure as the bilayer.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Stable ordering in Langmuir-Blodgett films.

Defects in the layering of Langmuir-Blodgett (LB) films can be eliminated by depositing from the appropriate monolayer phase at the air-water interface. LB films deposited from the hexagonal phase of cadmium arachidate (CdA2) at pH 7 spontaneously transform into the bulk soap structure, a centrosymmetric bilayer with an orthorhombic herringbone packing. A large wavelength folding mechanism acce...

متن کامل

Photoacoustic plasmon resonance spectra of Langmuir-Blodgett films

The surface plasmon spectra of Langmuir-Blodgett (LB) films have been investigated by combining photoacoustic technique with resonant attenuated total reflection spectroscopy. By this technique, the experimental PA angular spectra of cadmium stearate LB films have been obtained. According to the electromagnetic theory and considering the anisotropic properties of LB films, as well as based on t...

متن کامل

Interfacial behaviour of cubic silsesquioxane and silica nanoparticles in Langmuir and Langmuir–Blodgett films

In recent years fluorinated polyhedral oligomeric silsesquioxanes (POSS) have been established as useful for the fabrication of superhydrophobic surfaces, however little attention has been paid to their use for making ultrathin coatings by the Langmuir–Blodgett method. On the other hand, recently POSS compounds have been recognized as a new group of film-forming materials. In this study the int...

متن کامل

Waveguide evanescent field fluorescence microscopy: high contrast imaging of a domain forming mixed lipid Langmuir-Blodgett monolayer mimicking lung surfactant.

Waveguide evanescent field fluorescence (WEFF) microscopy is a new development that allows the imaging of contact regions between biological cells and their substratum, as well as imaging of ultrathin films such as monomolecular Langmuir-Blodgett (LB) films. Mixed-lipid monolayer systems mimicking lung surfactant were fabricated on waveguides using the LB technique and imaged by both WEFF and s...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • The Journal of chemical physics

دوره 123 21  شماره 

صفحات  -

تاریخ انتشار 2005