Hydroindation of allenes and its application to radical cyclization.
نویسندگان
چکیده
Hydroindation of allenes and radical cyclization of 1,2,7-trienes (allenenes) were accomplished by HInCl2 with high regioselectivity to afford a variety of cyclic compounds. The resulting vinylic indiums could be used for successive coupling reactions in a one-pot procedure. The use of HInCl2 generated slowly in situ is extremely effective for the radical cyclization.
منابع مشابه
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 6 11 شماره
صفحات -
تاریخ انتشار 2008