Polystyrene-supported N-methylthiourea: a convenient new reagent for the hydrogenolysis of bicyclic endoperoxides.
نویسندگان
چکیده
The single-step preparation of a polystyrene-bound N-methylthiourea and its use for the hydrogenolysis of bicyclic endoperoxides is described.
منابع مشابه
Polystyrene Supported [N-(Alanine) Sulfonamide]/Palladium Chloride: Synthesis, Characterization, for Heck Coupling Reactions
Abstract As a monomer, the [N-(alanine)] para-styrene sulfonamide (ASS) was prepared, from the reaction of para-styrene sulfonyl chloride and (S)-(+)-alanine in the presence of KOH 1M as a base, and CH3Cl was used as solvent. The monomer confirmed using FT-IR and 1H-NMR spectroscopy. Polystyrene [N-(alanine) sulfonamide] (PASS) was also prepared from the polymerization of [N-(alanine)] pa...
متن کاملPeroxynitric Acid: A Convenient Oxygen Source for Oxidation of Organic Compounds Catalyzed by Polyimide-Supported Manganese (III) Tetrakis(4-methoxylphenyl)porphyrin Acetate
In this work, a polyimide (PI) containing triazole units was synthesized using 3,5-diamino-1,2,4-triazole and pyromellitic dianhydride in N-methyl-2-pyrrolidinone. This polymer was used as the support of manganese (III) tetrakis(4-methoxylphenyl)porphyrin acetate to attain a heterogeneous catalyst; namely Mn(T4-OMePP)OAc@PI. The synthesized PI and Mn(T4-OMePP)OAc@PI were characterized by di...
متن کاملAminocyclopropanes as precursors of endoperoxides with antimalarial activity.
This contribution describes the synthesis of several novel bicyclic α-amino endoperoxides, including CF(3)-substituted compounds, prepared by the aerobic electrochemical oxidation of a family of bicyclic aminocyclopropanes. These, in turn, are readily synthesised by a titanium-mediated intramolecular cyclopropanation process (Kulinkovich-de Meijere reaction), starting from N-alkenyl amides that...
متن کاملOn the harmonic index of bicyclic graphs
The harmonic index of a graph $G$, denoted by $H(G)$, is defined asthe sum of weights $2/[d(u)+d(v)]$ over all edges $uv$ of $G$, where$d(u)$ denotes the degree of a vertex $u$. Hu and Zhou [Y. Hu and X. Zhou, WSEAS Trans. Math. {bf 12} (2013) 716--726] proved that for any bicyclic graph $G$ of order $ngeq 4$, $H(G)le frac{n}{2}-frac{1}{15}$ and characterize all extremal bicyclic graphs.In this...
متن کاملA green approach for the synthesis of 2-amino-4H-chromene derivatives using Polystyrene-Supported 1-Methylimidazolium tetrachloroferrate as an efficient heterogeneous catalyst in water
In this study, we reported facile and efficient synthesis of 2-amino-4H-chromenes that catalyzed by polystyrene-supported 1-methylimidazolium tetrachloroferrateas. The synthesis proceeds with various aldehydes under mild conditions and afford the target products with good to high yields.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 35 شماره
صفحات -
تاریخ انتشار 2005