3,3′-(m-Phenyl­enedi­oxy)diphthalonitrile

نویسندگان

  • Wei Lv
  • Kang Wang
  • Daopeng Zhang
  • Jianzhuang Jiang
  • Xiaomei Zhang
چکیده

In the title compound, C(22)H(10)N(4)O(2), the dihedral angles between the mean planes of the central benzene ring and the pendant rings are 79.20 (6) and 80.29 (6)°. The dihedral angle between the pendant rings is 10.27 (7)°.

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منابع مشابه

3,3′-Difluoro-4,4′-(p-phenyl­enedi­oxy)dibenzonitrile

The title compound, C(20)H(10)F(2)N(2)O(2), was synthesized from hydro-quinone and 3,4-difluoro-benzonitrile. The centroid of the central aromatic ring is on a crystallographic center of inversion. The dihedral angle between the central and terminal rings is 77.8 (3)°. In the crystal, chains linked by C-H⋯N bond occur.

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N,N′-Bis(4-methoxy­benzyl­idene)-4,4′-(m-phenyl­enedi­oxy)dianiline

Mol-ecules of the title compound, C(34)H(28)N(2)O(4), a Schiff base precursor for macrocycles, are located on a mirror plane. The C=N double bond is trans configured. Inter-molecular C-H⋯O inter-actions stabilize the crystal packing.

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The title compound, C(12)H(14)O(6), was prepared by the Williamson reaction of 1,4-dihydroxy-benzene and methyl chloro-acetate with phase-transfer catalysis. The compound lies on an inversion center. The structure is stabilized by weak C-H⋯π inter-actions.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010