Three p-carboxyphenyl groups possessing zinc porphyrins: efficient, stable, and cost-effective sensitizers for dye-sensitized solar cells.

نویسندگان

  • Ram B Ambre
  • Gao-Fong Chang
  • Chen-Hsiung Hung
چکیده

Zinc porphyrins possessing three p-carboxyphenyl anchoring groups with various substituents were prepared by a facile three-step route in good yields. Zn1NH3A with electron donating and anti-aggregation meso substituents has achieved the highest efficiency of 6.10%. These porphyrins with three p-carboxyphenyl groups are more stable toward photo-bleaching than their single anchoring group analogs.

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عنوان ژورنال:
  • Chemical communications

دوره 50 6  شماره 

صفحات  -

تاریخ انتشار 2014