Dinuclear lanthanide(III)/zinc(II) complexes with methyl 2-pyridyl ketone oxime.

نویسندگان

  • Nikolaos C Anastasiadis
  • Christina D Polyzou
  • George E Kostakis
  • Vlasoula Bekiari
  • Yanhua Lan
  • Spyros P Perlepes
  • Konstantis F Konidaris
  • Annie K Powell
چکیده

The first use of methyl 2-pyridyl ketone oxime (mpkoH) in zinc(II)/lanthanide(III) chemistry leads to the [ZnLn(mpko)3(mpkoH)3](ClO4)2 and [ZnLn(NO3)2(mpko)3(mpkoH)] families of dinuclear Zn(II)Ln(III) complexes displaying blue-green, ligand-based photoluminescence; the Zn(II)Dy(III) compound shows field-induced relaxation of magnetization.

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عنوان ژورنال:
  • Dalton transactions

دوره 44 46  شماره 

صفحات  -

تاریخ انتشار 2015